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Vinyl silane three oxygen radicals safety specifications
Vinyl silane three oxygen radicals safety specifications
The first part of chemicals and corporate logo
Chemicals Chinese name: English name: name of enterprise:
Mail address: editor: email address: contact phone number, fax number: enterprise emergency telephone: technical instruction code: product recommendations and restrictions on use: summary of the second part of the risk
Physical and chemical hazard: highly flammable, its vapor and air can form explosive mixture, caused an explosion of the burning flame, high heat. Strong reaction can occur with antioxidants. Velocity too fast, easy to generate and accumulate static electricity. Its vapor is heavier than air, can spread in the low to very far place, fire will fire back to combustion. The slow hydrolysis under the influence of water. Generate the corresponding silanol.
Health hazard: swallow cause gastrointestinal tract irritation and symptoms such as nausea, vomiting, diarrhea, inhale the steam
Can cause irritation to the respiratory tract, cause pulmonary edema, etc. Environmental hazards: has harm to the environment, on water, soil and air pollution. GHS risk categories: according to the general principles for the classification of chemicals and risk of the public (GB13690-2009) and chemical series standard of classification, the warning labels and warning instructions, this product belongs to flammable liquid, class 2; Acute toxicity - suction, category 4.
Tag elements:
Pictogram:
Risk warning word:
Dangerous information: highly flammable liquid and vapor; Inhaling harmful.
Guard:
Precaution: airtight operation, pay attention to ventilation. Operation mechanization and automation as soon as possible. Operation of
Member must receive special training, strictly abide by the operation procedures and Suggestions operators
Wear a self-priming filter type gas mask (half mask), with chemical safety goggles,
Wear a gas permeability overalls, a rubber oil resistant gloves. Away from fire and heat source,
Workplace smoking is strictly prohibited; Use explosion-proof ventilation systems and equipment, to prevent the steam
Leakage in the workplace air. Avoid contact with oxidant, pay attention to when filling
Velocity of not too high, and a grounding device to prevent electrostatic accumulation. In the light
Light discharge, prevent damage of packaging and container; Equipped with corresponding varieties and number of fire fighting apparatus
Material and the chroma of leakage in the air, recommends wearing filter type gas mask (half
Mask). When emergency rescue or evacuation, should wear air breathing apparatus or oxygen
Over 30 ℃, keep container seal. Should be with oxidant, edible chemicals,
Suitable for material. The third part of composition/information
Material ?
Dangerous components
Content, % the fourth part first aid measures mixture CASNo.
Skin contact: eye contact: mention eyelid, irrigate with flowing water or normal saline. Go to a doctor.
Inhalation: eating: drink enough water, vomiting. Go to a doctor.
Contact the main symptoms of the chemicals and impact on health, protect the rescuers advice: the fifth part fire protection measures
Special risk: extinguishing method and agent: 2
Out the leakage mouth fire, and rapidly take containment measures.
Protect fire personnel protective equipment: cooling, until the end of the fire, and protect the firemen fog water. The relevant personnel evacuation.
The sixth part leak emergency treatment
Homework personnel protective measures, protective equipment and emergency disposal procedures: environmental protection measures: leakage of chemicals asylum, removal method and the disposal of used materials: the seventh part disposal and storage operation
Operation note: observe operating instructions and suggest operators wear self-priming filter type gas mask (half mask), with chemical workplace smoking is strictly prohibited; Use explosion-proof ventilation systems and equipment, to prevent the steam leakage to the workplace
Place to prevent electrostatic accumulation. Light light discharge when handling to prevent packaging and container damage; Equipped with corresponding filter type gas mask (half mask). When emergency rescue or evacuation, should wear air breathing apparatus or storage precautions: store in a cool, ventilated warehouse, away from fire and heat source. The warehouse temperature is unfavorable use explosion-proof lighting, ventilation facilities. Banning the use of appropriate produce spark mechanical equipment and tools. Store the eighth part contact control/individual protection
Occupational exposure limit: China, no information.
Methods: biological limit: no data.
Methods: no data.
Engineering control: production process airtight, strengthen ventilated.
Respiratory protection: when the emergency rescue or evacuation, air respirator or oxygen breathing apparatus should be worn.
Eye protection: the body protection: wear protective material penetration overalls.
Hand protection: with oil resistant rubber gloves.
Other protection: work site no smoking, eating and drinking water, avoid drinking alcohol before work, after work, prior to employment and regular physical examination.
The ninth part of the physical and chemical properties
Appearance and odor: colorless liquid, no smell.
PH: relative density (water = 1) : 0.968
Relative vapor density (air = 1) : heat of combustion (KJ/mol) : no data.
Critical pressure (MPa) : flash point (℃) : 22
Spontaneous combustion temperature (℃) : odor thresholds: no data.
Solubility: melting/freezing point (℃) : at the beginning of boiling point, boiling point and boiling range (℃) : 123 saturation vapour pressure (mmHg, 25 ℃) : critical temperature (℃) : no data. Octanol/water partition coefficient of value: the explosion limit % (V/V) : 9 lower explosive limit % (V/V) : decomposition temperature (℃) : no data. Flammability: the tenth part of the stability and reactivity
Stability: stable.
Incompatible substances: antioxidant.
Avoid contact with the condition: fire, hot, humid air.
Risk response: with antioxidant intense reaction occurs, slow hydrolysis under the influence of water.
Dangerous breakdown products: carbon monoxide, carbon dioxide, silanol, etc.
The tenth part of toxicology data
Skin irritation/corrosion: eye stimulation or corrosion: no stimulation.
Breathing or skin allergy:
Germ cell respectively: carcinogenicity: no data.
Reproductive toxicity: specificity target organ system toxicity -- a single contact: no data.
Specific target organ system toxicity, repeated contact: inhalation hazard: upper respiratory tract irritation.
Section 12 ecology
Ecological toxicity: LC persistence and degradability: no data.
Potential biological cumulative: no data.
Mobility in soil: no data.
The 13th part of waste disposal
Waste disposal method:
- product: - dirty packing: it is recommended that contact the manufacturer, will return the empty container to producers.
Note: waste to prevent secondary pollution. The operator should wear appropriate individual protective equipment.
14 parts transportation information
The dangerous goods number: name: the United Nations transport inflammable liquid, not otherwise specified.
The risk classification:
Packing marks: category: Ⅱ class.
Packing method: bottle packaging, should be sealed tight, no leakage, the outer packing is carton, commonly enclosure should be firmly, without damage, Marine pollutant: no.
Shipping note: neat, box shall not exceed 5 floors. Pay attention to fire damp. Transportation route, according to the rules. The railway shipment. Transport transport vehicles should be equipped with corresponding varieties and number of fire equipment and leakage emergency treatment set static electricity. It is strictly prohibited and oxidant, amine, active metal powder mixed mix. Transit should prevent exposure device must be equipped with fire vehicle exhaust pipe, to ban the use of sparks easy generation equipment and tools to prohibit humping road transport. It is strictly prohibited to use wooden boats, concrete boats bulk transport.
15 part of regulatory information
Regulatory information: discharge, classification and mark the corresponding regulation: the production safety law of the People's Republic of China (June 29, 2002, the President of the People's Republic of China announced no. 70), the law of the People's Republic of China on the prevention and control of occupational diseases (October 27, 2001, the 24th meeting of the standing committee of the National People's Congress through the ninth world), the hazardous chemical materials safety management regulations (February 16, 2011 in the first of the state council
Full use chemical regulations (no. 1996 [1996] of the labor department is sent), the registration of dangerous chemicals \"pipe project order\" (GB/T16483-2008), \"dangerous goods packaging general technical conditions\" (GB packing classification method (GB/T15098-2008), the classification of dangerous goods and goods number 16 parts of other information
Time to fill out a form: on November 9, 2013
Department of filling: qufu chenguang chemical co., LTD. Security department
Data audit units: qufu chenguang chemical co., LTD. Office
Modify description: the SDS in accordance with the national standard \"the content of the chemical safety technical specifications and project order\" (GB/T16483-2008) compiled; GHS classification item risk because at present the country has not yet promulgated chemicals (GB13690-2009) in the general rules of the public, or chemical classification, warning label and warning that security specification series standard (GB20576 ~ 20602-2006, not including the GB20600-2006) of classification, after waiting for the chemical catalogs of GHS issued to adjust again.
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